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Light-Harvesting Ytterbium(III)–Porphyrinate–BODIPY Conjugates: Synthesis, Excitation-Energy Transfer, and Two-Photon-Induced Near-Infrared-Emission Studies

Authors

  • Tao Zhang,

    1. Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants, Committee, Hong Kong) and Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong (P. R. China), Fax: (+852) 3411–7348
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  • Xunjin Zhu,

    Corresponding author
    1. Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants, Committee, Hong Kong) and Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong (P. R. China), Fax: (+852) 3411–7348
    • Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants, Committee, Hong Kong) and Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong (P. R. China), Fax: (+852) 3411–7348
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  • Wai-Kwok Wong,

    Corresponding author
    1. Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants, Committee, Hong Kong) and Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong (P. R. China), Fax: (+852) 3411–7348
    • Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants, Committee, Hong Kong) and Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong (P. R. China), Fax: (+852) 3411–7348
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  • Hoi-Lam Tam,

    Corresponding author
    1. Department of Physics and Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong (P. R. China)
    • Department of Physics and Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong (P. R. China)
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  • Wai-Yeung Wong

    Corresponding author
    1. Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants, Committee, Hong Kong) and Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong (P. R. China), Fax: (+852) 3411–7348
    • Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants, Committee, Hong Kong) and Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong (P. R. China), Fax: (+852) 3411–7348
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Abstract

Based on a donor–acceptor framework, several conjugates have been designed and prepared in which an electron-donor moiety, ytterbium(III) porphyrinate (YbPor), was linked through an ethynyl bridge to an electron-acceptor moiety, boron dipyrromethene (BODIPY). Photoluminescence studies demonstrated efficient energy transfer from the BODIPY moiety to the YbPor counterpart. When conjugated with the YbPor moiety, the BODIPY moiety served as an antenna to harvest the lower-energy visible light, subsequently transferring its energy to the YbPor counterpart, and, consequently, sensitizing the YbIII emission in the near-infrared (NIR) region with a quantum efficiency of up to 0.73 % and a lifetime of around 40 μs. Moreover, these conjugates exhibited large two-photon-absorption cross-sections that ranged from 1048–2226 GM and strong two-photon-induced NIR emission.

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