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A Selective Palladium-Catalyzed Carbonylative Arylation of Aryl Ketones to Give Vinylbenzoate Compounds

Authors

  • Johannes Schranck,

    1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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  • Dr. Anis Tlili,

    1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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  • Dr. Helfried Neumann,

    1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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  • Pamela G. Alsabeh,

    1. Department of Chemistry, Dalhousie University, 6274 Coburg Road, P.O. Box 15000, Halifax NS B3H 4R2 (Canada)
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  • Prof. Dr. Mark Stradiotto,

    1. Department of Chemistry, Dalhousie University, 6274 Coburg Road, P.O. Box 15000, Halifax NS B3H 4R2 (Canada)
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  • Prof. Dr. Matthias Beller

    Corresponding author
    1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
    • Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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Abstract

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Preparation of enols: When treated with [{Pd(cinnamyl)Cl}2]/cataCXium A (nBuPAd2, Ad=adamantyl) under an atmosphere of CO, aryl ketones react with aryl halides in a carbonylative C[BOND]O coupling reaction to form (Z)-vinyl benzoates (see scheme).

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