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Bifunctionalization of Polyoxometalates with Two Different Organoimido Ligands



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Doubly modified: Polyoxometalates can incorporate a large number of different functionalities in a way that mixes the ligands in a one-pot reaction. A class of mixed organoimido bifunctionalized hexamolybdates is presented that involves two different moieties L1 and L2, namely, differing aromatic, aromatic and aliphatic, and aliphatic moieties.