Mixed Organotin(IV) Chalcogenides: From Molecules to Sn-S-Se Semiconducting Thin Films Deposited by Spin-Coating

Authors

  • Marek Bouška,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
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  • Lukáš Střižík,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
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  • Dr. Libor Dostál,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
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  • Aleš Růžička,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
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  • Prof. Dr. Antonín Lyčka,

    1. Research Institute for Organic Chemistry, VUOS a.s. 532 10, Pardubice (Czech Republic)
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  • Ludvík Beneš,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
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  • Milan Vlček,

    1. Institute of Macromolecular Chemistry of the Academy of Sciences of the Czech Republic v.v.i. Heyrovsky sq. 2, 120 06 Prague (Czech Republic)
    2. Present address: Joint Laboratory of Solid State Chemistry of Institute of Macromolecular Chemistry of the Academy of Sciences of the Czech Republic v.v.i. and the University of Pardubice, 532 10 Pardubice (Czech Republic)
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  • Jan Přikryl,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
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  • Petr Knotek,

    1. Institute of Macromolecular Chemistry of the Academy of Sciences of the Czech Republic v.v.i. Heyrovsky sq. 2, 120 06 Prague (Czech Republic)
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  • Prof. Tomáš Wágner,

    Corresponding author
    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
    • Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
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  • Dr. Roman Jambor

    Corresponding author
    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
    • Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Čs. legií 565, 532 10, Pardubice (Czech Republic)
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Abstract

original image

Put the right spin on it: Mixed monomeric organotin(IV) chalcogenides of the general formula L2Sn2EX2 containing two terminal Sn–X (X=Se, Te) bonds were prepared and were tested as potential single-source precursors for the deposition of semiconducting thin films. Spin-coating deposition of [{2,6-(Me2NCH2)2C6H3}SnSe]2(μ-S), as the useful single-source precursor, provided amorphous Sn-S-Se semiconducting thin films.

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