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Titanium-Catalyzed Intermolecular Hydroaminoalkylation of Conjugated Dienes

Authors

  • Till Preuß,

    1. Institut für Reine und Angewandte Chemie, Universität Oldenburg, Carl-von-Ossietzky-Straße 9–11, 26111 Oldenburg (Germany), Fax: (+49) 441-798-3329
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  • Wolfgang Saak,

    1. Institut für Reine und Angewandte Chemie, Universität Oldenburg, Carl-von-Ossietzky-Straße 9–11, 26111 Oldenburg (Germany), Fax: (+49) 441-798-3329
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  • Prof. Dr. Sven Doye

    Corresponding author
    1. Institut für Reine und Angewandte Chemie, Universität Oldenburg, Carl-von-Ossietzky-Straße 9–11, 26111 Oldenburg (Germany), Fax: (+49) 441-798-3329
    • Institut für Reine und Angewandte Chemie, Universität Oldenburg, Carl-von-Ossietzky-Straße 9–11, 26111 Oldenburg (Germany), Fax: (+49) 441-798-3329
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Abstract

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Ti me kangaroo down: Conjugated dienes undergo intermolecular hydroaminoalkylation in the presence of Ti catalyst [Ind2TiMe2] (Ind=η5-indenyl). This new reaction offers a highly atom-efficient approach to homoallylic amines from 1,3-butadienes.

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