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Ruthenium-Catalysed Synthesis of Functional Conjugated Dienes from Propargylic Carbonates and Silyl Diazo Compounds

Authors

  • Dr. Solenne Moulin,

    1. Organometallics: Materials and Catalysis, UMR 6226-Institut des Sciences Chimiques de Rennes, CNRS-Université de Rennes1 Campus de Beaulieu, 35042 Rennes (France), Fax: (+33) 223236939
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    • These authors contributed equally to this work.

  • Hanyu Zhang,

    1. Organometallics: Materials and Catalysis, UMR 6226-Institut des Sciences Chimiques de Rennes, CNRS-Université de Rennes1 Campus de Beaulieu, 35042 Rennes (France), Fax: (+33) 223236939
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    • These authors contributed equally to this work.

  • Suresh Raju,

    1. Organometallics: Materials and Catalysis, UMR 6226-Institut des Sciences Chimiques de Rennes, CNRS-Université de Rennes1 Campus de Beaulieu, 35042 Rennes (France), Fax: (+33) 223236939
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  • Dr. Christian Bruneau,

    Corresponding author
    1. Organometallics: Materials and Catalysis, UMR 6226-Institut des Sciences Chimiques de Rennes, CNRS-Université de Rennes1 Campus de Beaulieu, 35042 Rennes (France), Fax: (+33) 223236939
    • Organometallics: Materials and Catalysis, UMR 6226-Institut des Sciences Chimiques de Rennes, CNRS-Université de Rennes1 Campus de Beaulieu, 35042 Rennes (France), Fax: (+33) 223236939

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  • Dr. Sylvie Dérien

    Corresponding author
    1. Organometallics: Materials and Catalysis, UMR 6226-Institut des Sciences Chimiques de Rennes, CNRS-Université de Rennes1 Campus de Beaulieu, 35042 Rennes (France), Fax: (+33) 223236939
    • Organometallics: Materials and Catalysis, UMR 6226-Institut des Sciences Chimiques de Rennes, CNRS-Université de Rennes1 Campus de Beaulieu, 35042 Rennes (France), Fax: (+33) 223236939

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Abstract

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Ru being served? The reactions of propargylic carbonates with silyl diazo compounds in the presence of [Cp*RuCl(cod)] as a catalyst precursor led to the formation of dienyl carbonates in excellent yields under mild conditions (see scheme; Y=SiMe3).

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