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Synthesis, Structure, and Single-Molecule Magnetic Properties of Rare-Earth Sandwich Complexes with Mixed Phthalocyanine and Schiff Base Ligands

Authors

  • Hailong Wang,

    1. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083 (P. R. China, Fax: (+86) 10-6233-2462
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  • Wei Cao,

    1. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083 (P. R. China, Fax: (+86) 10-6233-2462
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  • Prof. Tao Liu,

    Corresponding author
    1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (P. R. China)
    • State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (P. R. China)
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  • Prof. Chunying Duan,

    1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (P. R. China)
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  • Prof. Jianzhuang Jiang

    Corresponding author
    1. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083 (P. R. China, Fax: (+86) 10-6233-2462
    • Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083 (P. R. China, Fax: (+86) 10-6233-2462
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Abstract

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Double- and quadruple-decker complexes of rare-earth metals with mixed phthalocyanine and Schiff base ligands have been synthesized and structurally and magnetically characterized. These complexes (see picture: Dy pink, Ca green, N blue, C black) extend the scope of sandwich-type tetrapyrrole-based rare-earth molecular materials.

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