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Covalent Modular Approach for Dimension-Controlled Self-Organization of Perylene Bisimide Dyes

Authors

  • Dr. Xu Lin,

    1. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039
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  • Misaki Hirono,

    1. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039
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  • Dr. Tomohiro Seki,

    1. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039
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  • Hiroki Kurata,

    1. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039
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  • Prof. Dr. Takashi Karatsu,

    1. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039
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  • Prof. Dr. Akihide Kitamura,

    1. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039
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  • Dr. Daiki Kuzuhara,

    1. Graduate School of Material Science, Nara Institute of Science and Technology (NAIST), 8916-5, Takayama-cho, Ikoma, Nara 630-0192 (Japan)
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  • Prof. Dr. Hiroko Yamada,

    1. Graduate School of Material Science, Nara Institute of Science and Technology (NAIST), 8916-5, Takayama-cho, Ikoma, Nara 630-0192 (Japan)
    2. CREST, JST, Chiyoda-ku, Tokyo 102-0075 (Japan)
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  • Dr. Tomonori Ohba,

    1. Graduate School of Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan)
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  • Dr. Akinori Saeki,

    1. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka 565-0871 (Japan)
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  • Shu Seki,

    1. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka 565-0871 (Japan)
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  • Prof. Dr. Shiki Yagai

    Corresponding author
    1. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039
    2. CREST, JST, Chiyoda-ku, Tokyo 102-0075 (Japan)
    • Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039
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Abstract

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Organogels: Dimerization of perylene bisimide dyes through an oligomethylene linker enabled the facile control over columnar and lamellar self-organized architectures by an odd/even effect with respect to the number of methylene groups. The difference in the self-organized architectures was shown to have an impact on their material morphologies, as well as charge-carrier mobilities (see scheme).

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