The selective α-CH bond activation of tetrahydrofuran by a cationic dialkyl zirconium complex in the presence of organosilane gave a stable α-tetrahydrofuranyl complex without any evidence for ring opening or other degradation reactions. Kinetic studies and DFT calculations suggest the intermediate formation of a cationic silyl zirconium complex.
Selective α-Metalation of THF by a Cationic Zirconium Complex Supported by an (NNNN)-Type Macrocyclic Ligand†
Version of Record online: 10 JUN 2013
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Chemistry - A European Journal
Volume 19, Issue 29, pages 9468–9471, July 15, 2013
How to Cite
Kulinna, H., Spaniol, T. P., Maron, L. and Okuda, J. (2013), Selective α-Metalation of THF by a Cationic Zirconium Complex Supported by an (NNNN)-Type Macrocyclic Ligand. Chem. Eur. J., 19: 9468–9471. doi: 10.1002/chem.201301202
- Issue online: 8 JUL 2013
- Version of Record online: 10 JUN 2013
- Manuscript Revised: 7 MAY 2013
- Manuscript Received: 29 MAR 2013
- Fonds der Chemischen Industrie
- Cluster of Excellence “Tailor-Made Fuels from Biomass”
- Institut Universitaire de France
- Calmip and CINES
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