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Keywords:

  • boron;
  • crystal structure;
  • gas storage;
  • imidazole;
  • metal–organic framework
Thumbnail image of graphical abstract

BIFing it up: The assembly between triangular HB(mim)3 units and tetrahedral Zn centers (see graphic) leads to the formation of a ctn-type BIF material with high porosity for gas storage and separation (mim=2-methylimidazolate).