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Keywords:

  • cluster compounds;
  • lanthanide oxide clusters;
  • lanthanides;
  • polytriazolate ligands;
  • supertetrahedra
Thumbnail image of graphical abstract

Supertetrahedral clusters: A family of lanthanide oxide supertetrahedral T3 {Ln20} clusters (Ln=Tb, Dy, Ho, Er; see figure) were obtained from the solvothermal reaction of lanthanide(III) salts with polytriazolate ligands that could be methylated and oxidized in situ.