Full Sensitivity and Enhanced Resolution in Homodecoupled Band-Selective NMR Experiments

Authors

  • Laura Castañar,

    1. Servei Ressonància Magnètica Nuclear, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain)
    2. Departament de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain)
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  • Dr. Pau Nolis,

    1. Servei Ressonància Magnètica Nuclear, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain)
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  • Prof. Albert Virgili,

    1. Departament de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain)
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  • Dr. Teodor Parella

    Corresponding author
    1. Servei Ressonància Magnètica Nuclear, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain)
    • Servei Ressonància Magnètica Nuclear, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain)===

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Abstract

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Fingers on the pulse: An NMR pulse scheme that provides full sensitivity in homodecoupled band-selective NMR spectroscopy experiments is proposed (see figure). The easy implementation of this HOBS scheme as a general building block into a great variety of multidimensional NMR experiments leads to pure-shift spectra with enhanced resolution and with the maximum attainable sensitivity.

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