Asymmetric Total Synthesis of (−)-Stenine and 9a-epi-Stenine (pages 13861–13870)
Prof. Dr. Hiromichi Fujioka, Kenji Nakahara, Naoyuki Kotoku, Yusuke Ohba, Yasushi Nagatomi, Tsung-Lung Wang, Yoshinari Sawama, Kenichi Murai, Kie Hirano, Tomohiro Oki, Shintaro Wakamatsu and Prof. Dr. Yasuyuki Kita
Version of Record online: 11 SEP 2012 | DOI: 10.1002/chem.201200376
Stereocontrolled synthesis: Stereocontrolled syntheses of (−)-stenine and 9a-epi-stenine have been developed by using a common cyclohexenone intermediate (see scheme). All six stereogenic centers in the cyclohexane ring were introduced with a high degree of stereoselectivity.