Preparative Organic Chemistry

ChemInform Abstract: Synthesis of (E)-1-Benzyloxy-3-fluoro-1,3-butadiene (I): A Novel Fluorinated Diene for Diels—Alder Reactions.

  1. Tsuyoshi Hayashi,
  2. Yoshinosuke Usuki,
  3. Yosuke Wakamatsu,
  4. Hideo Iio

Article first published online: 14 MAR 2011

DOI: 10.1002/chin.201114027

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ChemInform

ChemInform

Volume 42, Issue 14, page no, April 5, 2011

Additional Information

How to Cite

Hayashi, T., Usuki, Y., Wakamatsu, Y. and Iio, H. (2011), ChemInform Abstract: Synthesis of (E)-1-Benzyloxy-3-fluoro-1,3-butadiene (I): A Novel Fluorinated Diene for Diels—Alder Reactions.ChemInform, 42: no. doi: 10.1002/chin.201114027

Author Information

  1. Dep. Mater. Sci., Fac. Sci., Osaka City Univ., Sumiyoshi, Osaka 558, Japan

Publication History

  1. Issue published online: 14 MAR 2011
  2. Article first published online: 14 MAR 2011

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Keywords:

  • cycloaddition reactions;
  • cyclohexane derivatives;
  • pyran derivatives;
  • pyridazine derivatives

Abstract

The title diene (I), a fluorinated analogue of Kitahara—Danishefsky′s diene, smoothly reacts with various dienophiles to furnish useful 1-fluorocyclohexene derivatives in good yields.

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