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Regular Article -- Dedicated to Prof. K. Barry Sharpless

Ligand-accelerated cadmium-catalyzed asymmetric allylation reactions in aqueous media†

  1. Shū Kobayashi*,
  2. Naohiro Aoyama,
  3. Kei Manabe

Article first published online: 27 DEC 2002

DOI: 10.1002/chir.10154

Issue

Chirality

Chirality

Volume 15, Issue 2, pages 124–126, 2003

Additional Information

How to Cite

Kobayashi, S., Aoyama, N. and Manabe, K. (2003), Ligand-accelerated cadmium-catalyzed asymmetric allylation reactions in aqueous media. Chirality, 15: 124–126. doi: 10.1002/chir.10154

Author Information

  1. Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan

*Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

  1. †

    Dedicated to Professor K. Barry Sharpless, recipient of the 2000 Chirality Medal

Publication History

  1. Issue published online: 27 DEC 2002
  2. Article first published online: 27 DEC 2002
  3. Manuscript Accepted: 15 AUG 2002
  4. Manuscript Received: 21 JUN 2002

Funded by

  • CREST and SORST
  • Japan Science and Technology Corporation (JST)
  • Grant-in-Aid for Scientific Research from the Japan Society of the Promotion of Science

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Keywords:

  • ligand acceleration;
  • asymmetric catalysis;
  • aqueous reaction;
  • allyltin;
  • chiral ligand

Abstract

Catalytic asymmetric allylation of aldehydes with allyltributyltin in aqueous media has been realized using combinations of cadmium bromide and chiral diamine ligands. These ligands were found to accelerate the reactions significantly. Chirality 15:124–126, 2003. © 2003 Wiley-Liss, Inc.

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