Deracemization of an axially chiral biphenylic derivative as a tool for investigating chiral recognition in self-assemblies
Article first published online: 7 APR 2003
Copyright © 2003 Wiley-Liss, Inc.
Volume 15, Issue 5, pages 441–447, 2003
How to Cite
Borocci, S., Ceccacci, F., Galantini, L., Mancini, G., Monti, D., Scipioni, A. and Venanzi, M. (2003), Deracemization of an axially chiral biphenylic derivative as a tool for investigating chiral recognition in self-assemblies. Chirality, 15: 441–447. doi: 10.1002/chir.10230
- Issue published online: 7 APR 2003
- Article first published online: 7 APR 2003
- Manuscript Accepted: 8 JAN 2003
- Manuscript Received: 1 OCT 2002
- cationic surfactant;
Two diastereomeric cationic surfactants derived from L-proline, in which the second chiral center is a quaternary nitrogen, have been separated and fully characterized. The recognition properties of the aggregates formed by the two diastereomeric surfactants have been investigated by circular dichroism and 1H NMR through deracemization of racemic 2-carboxy-2′-dodecyloxy-6-nitrobiphenyl. Chirality 15:441–447, 2003. © 2003 Wiley-Liss, Inc.