HPLC with carbohydrate carbamate chiral phases: Influence of chiral phase structure on enantioselectivity
Article first published online: 17 SEP 2004
Copyright © 1994 Wiley-Liss, Inc.
Volume 6, Issue 2, pages 135–140, 1994
How to Cite
Matlin, S. A., Tiritan, M. E., Crawford, A. J., Cass, Q. B. and Boyd, D. R. (1994), HPLC with carbohydrate carbamate chiral phases: Influence of chiral phase structure on enantioselectivity. Chirality, 6: 135–140. doi: 10.1002/chir.530060214
- Issue published online: 17 SEP 2004
- Article first published online: 17 SEP 2004
- Manuscript Accepted: 17 NOV 1993
- Manuscript Received: 21 SEP 1993
- trans-stilbene oxide;
- chiral sulfoxides;
The enantioselective resolution of trans-stilbene oxide and of 23 chiral sulfoxides was investigated on cellulose and amylose tris(arylcarbamate) stationary phases coated on aminopropylated 7 μm spherical silica with 500 Å diameter pores. Cellulose tris-(3,5 dimethylphenylcarbamate) showed good resolving power for many of the sulfoxides and amylose tris-(3,5 dimethoxyphenylcarbamate) showed advantages for the resolution of certain sulfoxides which were not separated on other phases. © 1994 Wiley-Liss, Inc.