Article

Structural Effect on Eu(fod)3-Catalyzed Rearrangement of Allylic Esters†

  1. Wei-Min Dai1,
  2. Wing-Leung Mak2

Article first published online: 26 AUG 2010

DOI: 10.1002/cjoc.20030210713

Issue

Chinese Journal of Chemistry

Chinese Journal of Chemistry

Volume 21, Issue 7, pages 772–783, July 2003

Additional Information

How to Cite

Dai, W.-M. and Mak, W.-L. (2003), Structural Effect on Eu(fod)3-Catalyzed Rearrangement of Allylic Esters. Chin. J. Chem., 21: 772–783. doi: 10.1002/cjoc.20030210713

Author Information

  1. 1

    Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, China

  2. 2

    Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China

  1. †

    Dedicated to Professor ZHOU Wei-Shan on the occasion of his 80th birthday.

Publication History

  1. Issue published online: 26 AUG 2010
  2. Article first published online: 26 AUG 2010
  3. Manuscript Accepted: 25 APR 2003
  4. Manuscript Revised: 22 APR 2003
  5. Manuscript Received: 1 APR 2003

Funded by

  • Department of Chemistry, The Hong Kong University of Science and Technology.

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

Get PDF (1143K)

Keywords:

  • lanthanide;
  • allylic ester;
  • rearrangement

Abstract

A detail study on the Eu(fod)3-catalyzed rearrangement of allylic esters was described. A significant effect of the substituents at the allylic backbone was observed. The migrating tendency of the alkoxyacetates was established in the order of p-CF3C6H4CH2OCH2CO2 > MeOCH2CO2 > PhCH2OCH2CO2 > p-MeOC6H4CH2OCH2CO2.

Get PDF (1143K)