Group IV M-POSS (M=Zr, Hf) Coordination Polymers

Authors

  • Zhijun Wei,

    1. Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China
    2. Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Sichuan 621900, China
    Search for more papers by this author
  • Hongbo Ren,

    1. Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Sichuan 621900, China
    Search for more papers by this author
  • Lin Zhang,

    Corresponding author
    1. Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Sichuan 621900, China
    • Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Sichuan 621900, China
    Search for more papers by this author
  • Meiming Luo

    Corresponding author
    1. Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China
    • Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China, Tel.: 0086-028-85462021; Fax: 0086-028-85462021
    Search for more papers by this author

Abstract

The synthesis and characterization of Zr-POSS and Hf-POSS coordination polymers were reported. The IR data and the solid-state 29Si MAS NMR indicated the existence of Si[BOND]O[BOND]M linkage. The polarized optical microscopy images and the XRD data suggested their crystalline nature.

Ancillary