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Synthesis of 2-Aminoindole Derivatives with Hantzsch Ester Catalyzed by Pd/C

  1. Ruiguang Xing1,*,
  2. Qiuping Tian2,
  3. Qiang Liu2,
  4. Yanan Li1

Article first published online: 17 DEC 2012

DOI: 10.1002/cjoc.201200834

Issue

Chinese Journal of Chemistry

Chinese Journal of Chemistry

Volume 31, Issue 2, pages 263–266, February, 2013

Additional Information

How to Cite

Xing, R., Tian, Q., Liu, Q. and Li, Y. (2013), Synthesis of 2-Aminoindole Derivatives with Hantzsch Ester Catalyzed by Pd/C. Chin. J. Chem., 31: 263–266. doi: 10.1002/cjoc.201200834

Author Information

  1. 1

    College of Rare Earth, Inner Mongolia University of Science & Technology, Baotou, Inner Mongolia 014010, China

  2. 2

    State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000, China

*College of Rare Earth, Inner Mongolia University of Science & Technology, Baotou, Inner Mongolia 014010, China, Tel.: 0086-472-5951536; Fax: 0086-472-5951536

Publication History

  1. Issue published online: 18 FEB 2013
  2. Article first published online: 17 DEC 2012
  3. Manuscript Accepted: 13 NOV 2012
  4. Manuscript Received: 17 AUG 2012

Funded by

  • the National Natural Science Foundation of China. Grant Number: 21172102

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Keywords:

  • 2-aminoindole;
  • reductive cyclization;
  • Hantzsch ester;
  • palladium on carbon

Abstract

Catalytic hydrogenation of 2-cyano-2-(2-nitrophenyl)acetates bearing an electron withdrawing substituent to the nitrile, using Hantzsch ester catalyzed by Pd/C, affords 2-aminoindoles in good to excellent yields.

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