Chinese Journal of Chemistry

Cover image for Chinese Journal of Chemistry

March, 2009

Volume 27, Issue 3

Pages 445–610

  1. Full Papers

    1. Top of page
    2. Full Papers
    3. Notes
    4. Addition and Correction
    1. Controlled-release of Avermectin from Organically Modified Hydrotalcite-like Compound Nanohybrids (pages 445–451)

      Depeng QIU, Yonghai LI, Xiying FU, Zhen JIANG, Xinyan ZHAO, Tian WANG and Wanguo HOU

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990073

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      The intercalation of avermectin (AVM) into sodium dodecyl sulfate (SDS) modified hydrotalcite-like compounds (HTlc) was carried out using an evaporating solvent enhanced intercalation method to obtain AVM-SDS-HTlc nanohybrids. It was found that the nanohybrids could well control the release of avermectin, showing that the nanohybrids are a potential pesticide controlled-release formulation.

    2. A Kinetically Mechanistic Investigation of Oxidation of 1,4-Butanediamine by Ag(III) Complex in Alkaline Medium (pages 452–454)

      Changying SONG, Jinhuan SHAN, Shigang Shen and Hanwen Sun

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990074

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      Kinetics and mechanism of oxidation of 1,4-butanediamine by Ag(III) complex was studied spectrophotometrically in alkaline medium at constant ion strength.

    3. Theoretical Studies on the Infrared Vibrational Spectra, Thermodynamic Properties and Nuclear Magnetic Resonance Spectra for Polynitro-1,3-bishomopentaprismanes (pages 455–468)

      Limei QIU, Xuedong GONG, Guixiang WANG, Jian ZHENG and Heming XIAO

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990075

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      Based on the optimized geometrical results at the B3LYP/6-31G∗ level, the IR spectra, thermodynamic properties, as well as 13C and 1H NMR chemical shifts for a series of polynitro-1,3-bis-homopenta-prismanes have been calculated and discussed.

    4. Bending of the Flexible Spacer Chain of Gemini Surfactant Induced by Hydrophobic Interaction (pages 469–471)

      Yi YOU, Rong JIANG, Tingting LING and Jianxi ZHAO

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990076

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      The enhanced hydrophobic interaction between the alkyl tails and the spacer chain can effectively induce the bending of the flexible alkylene spacer toward the air-side.

    5. Molecular Simulation Study of Hexane Diffusion in Dynamic Metal-Organic Frameworks (pages 472–478)

      Chunyu XUE and Chongli ZHONG

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990077

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      This work shows that the diffusion pathway of hexane was largely influenced by loading.

    6. Synthesis and Structural Characterization of a New 2D Coordination Polymer [Cu(pzta)2]n (pages 479–482)

      Xin HU, Cong LIU, Yongjiang WANG and Jixi GUO

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990078

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      A new copper(II) tetrazolate coordination polymer [Cu(pzta)2]n (1) (pzta=5-pyrazinyltetrazolate) was prepared from the hydrothermal reaction of Cu(OAc)2·H2O with NaN3 and pyrazinecarbonitrile (pzCN) in the presence of ethanol, and characterized by elemental analysis, IR, TGA and X-ray crystallography. The X-ray diffraction analysis of 1 shows that the compound crystallizes in the monoclinic system with space group P2(1)/c and Cu(II) ion center is six-coordinated by four different pzta ligands. The complex 1 features a 2D tetrazole coordination polymer. The thermal analysis of 1 shows that the decomposition of the complex occurs in two regions.

    7. Catalytic Combustion of Ethyl Acetate over Nanostructure Cobalt Supported ZSM-5 Zeolite Catalysts (pages 483–488)

      Aligholi NIAEI, Dariush SALARI, Seyed Ali HOSSEINI, Masumeh KHATAMIAN and Azadeh JODAEL

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990079

      Gas phase catalytic combustion of ethyl acetate, as one of volatile organic compounds (VOC), was studied on nanostructure ZSM-5, HZSM-5 and Co-ZSM-5 with different cobalt loadings. Nanostructure of ZSM-5 was determined by XRD, SEM and TEM. Catalytic studies were carried out under atmospheric pressure in a fixed bed reactor. Results showed that the Co-ZSM-5 catalysts had better activity than others and at temperatures below 350 °C, amount of Co loading was more effective on catalytic activity. The order of conversion of ethyl acetate over different Co loading is as follows: Co-ZSM-5 (0.75 wt%)<Co-ZSM-5 (1.5 wt%)<Co-ZSM-5 (15 wt%)<Co-ZSM-5 (2.8 wt%). Besides the higher the inlet concentration of ethyl acetate, the lower the conversion yield, and oxygen concentration in catalytic oxidation conditions has not so large influence on conversion. Furthermore, the presence of water vapor in inlet gaseous feed has an inhibitive effect on ethyl acetate conversion and at the temperatures above 400 °C, the effect decreases.

    8. Flame-retardancy of a Cellulosic Fabric by the Application of Synergistic Effect between Ammonium Bromide and Antimony(III) Oxide (pages 489–493)

      Seyed Morteza MOSTASHARI and Hadi Fallah MOAFI

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990080

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      The outcomes of TG curves concerning the flame-retarded supported samples show the similar three stages but with lower decomposition temperatures and mass. The figure also demonstrates TG curve of the flame-retarded cotton fiber and the combined curves respectively. It is obvious that the decomposition temperature of the treated cotton substrate with Sb2O3 is higher compared with untreated one, indicating no influence occurred by using it as a dehydrating agent. Note that both ammonium bromide and its synergy with antimony(III) oxide illustrated a significant role as a dehydrating agent to catalyze the dehydration of the cellulosic substrate, since they lowered the dehydrating temperature around 300 °C.

    9. Synthesis, Crystal Structure and Thermal Behavior of Co(en)3[B4O5(OH)4]Cl·3H2O and [Ni(en)3][B5O6(OH)4]2·2H2O (pages 494–500)

      Lijuan ZHENG, Jianjian ZHANG and Zhihong LIU

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990081

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      All components of Co(en)33+, [B4O5(OH)4]2−, Cl and H2O for Co(en)3- [B4O5(OH)4]Cl·3H2O are linked together to form a 3D supramolecular network through four kinds of hydrogen bonds, O–H···O, O–H···Cl, N–H···Cl and N–H···O and the three crystalline water molecules form a zigzag water-chain through O–H···O.

    10. Synthesis and Crystal Structure of an Unprecedented Supramolecular Complex [Co(µ2-ClO4)2(H2O)2]·2MA (pages 501–504)

      Jing XU, Zhengshuai BAI and Weiyin SUN

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990082

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      A new 3D supramolecular framework [Co(µ2-ClO4)2(H2O)2]·2MA linked by hydrogen bonding and π-π interactions is reported.

    11. Understanding the Effect of Corners: Adsorption of Fluids in Three Different Shapes of Nanopores (pages 505–512)

      Xiaohong SHAO, Congcong MA, Dapeng CAO and Wenchuan WANG

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990083

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      Adsorption of nitrogen, hydrogen and methane in square and rectangular nanopores of various sizes has been studied by grand canonical Monte Carlo simulations (GCMC). By comparison of three kinds of potential models, it was found that the site-site model was more rational, which was therefore used in the work. Adsorption behavior of fluids in square, rectangular and cylindrical pores at T=77 K was compared. Prewetting was found in the corners of the square and rectangular pores, which is absent in the cylindrical pores. Adsorption of hydrogen and methane in the three kinds of pores was compared. Among them, the adsorption uptake of hydrogen in the square pore is highest, especially at low pressures, because the effect of potential superposition in the "corners" makes an important contribution to hydrogen adsorption. The results indicate that the presence of corners has a profound effect upon the adsorption and phase behavior of fluids at low pressures.

    12. Fluorescence Quenching of Pheophytin-a by Copper(II) Ions (pages 513–517)

      Mingbo HU, Huaixiang LI, Lusheng CHEN, Huaibin ZHANG and Chuan DONG

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990084

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      The fluorescence intensity of the pheophytin-a acetone solution decreases linearly with the copper(II) ion concentration in the µmol·dm−3 range.

    13. A Novel Spectrophotometric Method for the Determination of Isoniazid Using Cu(II) as Spectroscopic Probe Ion (pages 518–522)

      Hua ZHANG, Yan ZHANG, Xianjun WEI, Xinzhen DU and Quanmin LI

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990085

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      In the presence of SCN, Cu(II) was reduced to Cu(I) by isoniazid. The resulting Cu(I) reacted with SCN to develop white emulsion precipitate CuSCN, which was floated on the surface of water when NaNO3 was added into the solution. By determining the amount of residual Cu(II) in the water phase, the amount of isoniazid could be obtained.

    14. Homogeneous DNA Detection Based on Fluorescence Quenching by Nanoparticles in Single-step Format: Target-Induced Configuration Transform (pages 523–528)

      Songbai ZHANG, Zaisheng WU, Ming XIE, Guoli SHEN and Ruqin YU

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990086

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      3′ FAM-labeled oligonucleotides were immobilized on the gold nanoparticles via 5′-SH. Specific hybridization with the complementary target makes the probe sequence bend to form an arch-like structure. The fluorophore and gold nanoparticles are brought in close proximity, resulting in fluorescence quenching.

    15. Thermodynamics and Extra-thermodynamics of Bacillus subtilis α-Amylase in Some Chromatographic Systems (pages 529–540)

      Liujiao BIAN, Xiaohua WANG, Xiaoyan YANG, Li LIU and Chao CHEN

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990087

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      The thermodynamics and extra-thermo- dynamics of Bacillus subtilis α-amylase in some chromatographic systems were studied. It was found that their adsorption procedures were driven by both of the enthalpy change and the entropy change on some chromatographic media, while on some other chromatographic media, their adsorption procedures were driven only by the entropy change; and for α-amylases on a RP-C18 reversed-phase medium (⋄), a Zn-chelated Sepharose fast-flow affinity medium (□), a WCX-1 cation-exchange media (Δ), a PEG-400 hydrophobic medium (◯) and a modified PEG-400 medium (∗), their enthalpy-entropy compensation relationships lay on the same straight-line and their enthalpy changes could be compensated only with their entropy changes rising from their conformational change.

    16. Identification of Phenylethanoid Glycosides in Plant Extract of Plantago asiatica L. by Liquid Chromatography-Electrospray Ionization Mass Spectrometry (pages 541–545)

      Li LI, Chunming LIU, Zhiqiang LIU, Rong TSAO and Shuying LIU

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990088

      The present work describes a liquid chromatography-electrospray ionization mass spectrometry (LC-ESI-MS) method for rapid identification of phenylethanoid glycosides in plant extract from Plantago asiatica L. By using a binary mobile phase system consisting of 0.2% acetic acid and acetonitrile under gradient conditions, a good separation was achieved on a reversed-phase C18 column. The [M–H] ions, the molecular weights, and the fragment ions of phenylethanoid glycosides were obtained in the negative ion mode using LC-ESI-MS.

    17. Simultaneous Spectrophotometric Determination of Three Tolualdehyde Isomers by Artificial Neural Networks and Its Comparison with Partial Least Squares (pages 546–550)

      Huiwen FANG, Hui LI, Yanwei LI, Jing ZHAO and Jian XU

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990089

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      The concentration of every component in the mixture can be obtained by using artificial neural networks and partial least squares to carry out analysis on absorption spectra of the mixture.

    18. Toxicity Effect of Pb(II) on Two Different Kinds of Microbes Measured by Microcalorimetry (pages 551–556)

      Nan GAI, Jun YAO, Lin TIAN, Huilun CHEN, Yong ZHOU, Fei WANG, Yanjiao CHEN, Haiyan CHEN, Ke CHEN, Polonca TREBSE and Gyula ZARAY

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990090

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      Microcalorimetric was used to analyze the toxic action of Pb2+ on the metabolic activities. Pb2+ has a stimulating effect on Candida humicola and Bacillus subtilis growth at low concentration and an inhibitory influence at high concentration. This investigation aims at evaluating the toxic action of Pb(II) on the Candida humicola and Bacillus subtilis by microcalorimetric technique.

    19. Pharmacophore Identification of Hydroxamate HDAC 1 Inhibitors (pages 557–564)

      Liqin YU, Fei LIU, Yadong CHEN and Qidong YOU

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990091

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      A three-dimensional pharmacophore model was developed based on 24 currently available hydroxamate histone deacetylase inhibitors in Catalyst software package.

    20. Synthesis and Biological Activities of Novel Thiophosphoryl Oximates Containing Thiazole and 1,2,3-Triazole Rings (pages 565–568)

      Xiaofei ZHU and Deqing SHI

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990092

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      A series of novel thiophosphoryl oximates containing thiazole and 1,2,3-triazole rings 4 were synthesized by the reactions of 1-{1-[(2-chlorothiazol-5-yl)methyl]-5-methyl-1H-1,2,3-triazol-4-yl}ethanone oxime with various asymmetric thiophosphoryl chlorides. The results of preliminary bioassay indicate that some of the title compounds possess moderate insecticidal and fungicidal activities

    21. Application of Heteropolyacids as Heterogeneous and Recyclable Catalysts for One-Pot Synthesis of 3-Cyanopyridine Derivatives (pages 569–572)


      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990093

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      A simple, clean and environmentally benign route to the synthesis of 3-cyanopyridines is described via a one-pot multi-component reaction of 3,4-dimethoxyacetophenone, malonitrile or ethylcyanoacetate, aldehyde and ammonium acetate using heteropolyacids as heterogeneous and recyclable catalysts in very good yields.

    22. Synthesis, Structure and Biological Activities of Some Novel Anthranilic Acid Esters Containing N-Pyridylpyrazole (pages 579–586)

      Weili DONG, Junying XU, Lixia XIONG, Xinghai LIU and Zhengming LI

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990095

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      A novel series of anthranilic acid esters containing N-pyridylpyrazole were designed and synthesized. Their structures were determined by IR 1H NMR, MS and elemental analysis, and their insecticidal activities against Mythimna separata Walker and Culex pipiens pallens were tested.

    23. Ionic liquid-H2O Resulting in a Highly Chemoselective Oxidation of Benzylic Alcohols in the Presence of Aliphatic Analogues Catalyzed by Immobilized TEMPO (pages 587–592)

      Ruijun HU, Ming LEI, Hegeng WEI and Yanguang WANG

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990096

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      In ionic liquid [bmim][PF6]-H2O, a highly chemoselective oxidation of benzylic alcohols in the presence of aliphatic ones to the corresponding hydroxyl benzyl aldehydes and ketones was allowed in high yields using a facile and effective catalytic oxidation system NCS/NaBr/IL-TEMPO (ionic liquid immobilized TEMPO). The medium, [bmim][PF6], together with the catalyst IL-TEMPO could be easily recycled for ten runs without any influence on the efficacy of the reaction in terms of yield and selectivity of the product.

    24. Synthesis and Antiviral Activities of Chiral Thiourea Derivatives (pages 593–601)

      Zhikun YAN, Xuejian CAI, Xuan YANG, Baoan SONG, Zhuo CHEN, S. Pinaki BHADURY, Deyu HU, Linhong JIN, Wei XUE and Ping LU

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990097

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      Some novel chiral thiourea derivatives have been synthesized in high yield in ionic liquid [Bmim]PF6. The preliminary bioassay showed that some of the chiral thiourea analogues exhibited moderate in vivo antiviral activities against TMV at a concentration of 500 mg/L.

  2. Notes

    1. Top of page
    2. Full Papers
    3. Notes
    4. Addition and Correction
    1. Experimental and Theoretical Analyses of Complex Bis[2,4-di(p-nitrophenyl)-1,3,5-triazapentadienato]Cu(II) Synthesized in situ (pages 602–606)

      Xiaofeng XIE, Sanping CHEN, Zhengyi WEN and Shengli GAO

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990098

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      Hydrothermal in situ reaction of 4-nitrobenzonitrile, ammonia and Cu(II) salts yielded complex bis[2,4-di(p-nitrophenyl)-1,3,5-triazapentadienato]Cu(II). DFT calculation shows that nitrobenzonitrile as the starting material benefits for the thermodynamic stabilization of the target.

    2. Dehydration of Oximes to Nitriles Catalyzed by a Green Heteropolyacid Catalyst: Preyssler's Anion, [NaP5W30O110]14− (pages 607–609)

      Majid M. HERAVI, Sodeh SADJADI, Rahim HEKMATSHOAR, Hossein A. OSKOOIE and Fatemeh F. BAMOHARRAM

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990099

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      A mild, simple, and high yielding procedure for the direct conversion of oximes to nitriles has been developed using heteropolyacid in acetic acid. Aromatic and aliphatic aldoximes were converted to the corresponding nitriles in the presence of Preyssler type heteropolyacid, which could be reused several times without any appreciable loss of activity.

  3. Addition and Correction

    1. Top of page
    2. Full Papers
    3. Notes
    4. Addition and Correction
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      Preparation of Magnetic Photocatalyst TiO2 Supported on NiFe2O4 and Effect of Magnetic Carrier on Photocatalytic Activity (page 610)

      Shi-Hong XU, Dao-Lun FENG, Deng-Xin LI and Wen-Feng SHANGGUAN

      Version of Record online: 2 APR 2009 | DOI: 10.1002/cjoc.200990100