Chinese Journal of Chemistry

Cover image for Vol. 32 Issue 6

Special Issue: Solar Cells and Solar Fuels

June, 2014

Volume 32, Issue 6

Pages 457–552

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Communications
    6. Full Papers
    1. You have free access to this content
      Cover Picture: An [Fe-Fe]-Hydrogenase Mimic Immobilized on MCM-41 for the Photochemical Production of Hydrogen in Pure Water (Chin. J. Chem. 6/2014) (page 457)

      Wen Wang, Tianjun Yu, Yi Zeng, Jinping Chen and Yi Li

      Article first published online: 23 JUN 2014 | DOI: 10.1002/cjoc.201490012

      Thumbnail image of graphical abstract

      The cover picture shows a convenient approach for the application of water-insoluble hydrogenase mimics in water. A hydrophobic hydrogenase mimic has been successfully applied to the photochemical production of hydrogen in pure water by immobilization of it into MCM-41 with an iridium compound [Ir(ppy)2bpy]Cl and triethylamine as the photosensitizer and the sacrificial electron donor, respectively. The immobilization stabilizes hydrogenase mimic, which endows the catalytic system good catalytic activity. The present study provides a general strategy for applying hydrophobic artificial catalysts in pure water by using mesoporous molecular. More details are discussed in the article by Li et al. on page 479–484.

  2. Editorial

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Communications
    6. Full Papers
    1. You have free access to this content
      Special Issue of "Solar Cells and Solar Fuels" (page 459)

      Li-Zhu Wu

      Article first published online: 23 JUN 2014 | DOI: 10.1002/cjoc.201490013

  3. Contents

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Communications
    6. Full Papers
    1. Contents: Chin. J. Chem. 6/2014 (pages 460–464)

      Article first published online: 23 JUN 2014 | DOI: 10.1002/cjoc.201490014

  4. Communications

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Communications
    6. Full Papers
    1. Photo-Induced Water Oxidation Based on a Mononuclear Cobalt(II) Complex (pages 467–473)

      Hongyan Wang, Yongbin Lu, Edgar Mijangos and Anders Thapper

      Article first published online: 17 FEB 2014 | DOI: 10.1002/cjoc.201300856

      Thumbnail image of graphical abstract

      CoCl2·6H2O reacting with TPA (tris(2-pyridylmethyl)amine) in CH3CN can smoothly convert into the mononuclear cobalt(II) complex [Co(TPA)Cl]Cl, which can act as an efficient catalyst for photo-induced water oxidation assisted by a photosensitizer and an electron acceptor.

    2. Highly Efficient Dye-sensitized Solar Cells by Co-sensitization of Organic Dyes and Co-adsorbent Chenodeoxycholic Acid (pages 474–478)

      Yinni Wei, Zhisheng Wu, Zhongwei An, Xinbing Chen, Pei Chen and Qianfeng Liu

      Article first published online: 13 JUN 2014 | DOI: 10.1002/cjoc.201400190

      Thumbnail image of graphical abstract
  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Communications
    6. Full Papers
    1. An [Fe-Fe]-Hydrogenase Mimic Immobilized on MCM-41 for the Photochemical Production of Hydrogen in Pure Water (pages 479–484)

      Wen Wang, Tianjun Yu, Yi Zeng, Jinping Chen and Yi Li

      Article first published online: 22 APR 2014 | DOI: 10.1002/cjoc.201400083

      Thumbnail image of graphical abstract

      Hy@MCM-41, constructed by a [Fe-Fe]-hydrogenase mimic (Hy) immobilized on K+-exchanged molecular sieve K-MCM-41, was applied to the light-induced hydrogen production in pure water with [Ir(ppy)2bpy]Cl and triethylamine as the photosensitizer and the sacrificial electron donor, respectively, exhibiting good stability and catalytic activity.

    2. One-Pot Hydrothermal Synthesis and Photocatalytic Hydrogen Evolution of Pyrochlore Type K2Nb2O6 (pages 485–490)

      Jingjing Wu, Chao Zhou, Yufei Zhao, Lu Shang, Tong Bian, Lei Shao, Feng Shi, Li-Zhu Wu, Chen-Ho Tung and Tierui Zhang

      Article first published online: 17 FEB 2014 | DOI: 10.1002/cjoc.201300817

      Thumbnail image of graphical abstract

      Octahedral-shaped K2Nb2O6 with pyrochlore structure prepared by a facile and eco-friendly one-pot hydrothermal method showed high photocatalytic H2 production under UV light irradiation.

    3. High-Performance Cobalt Selenide and Nickel Selenide Nanocomposite Counter Electrode for Both Iodide/Triiodide and Cobalt(II/III) Redox Couples in Dye-Sensitized Solar Cells (pages 491–497)

      Zaiwei Wang, Hongxia Xu, Zhongyi Zhang, Xinhong Zhou, Shuping Pang and Guanglei Cui

      Article first published online: 22 APR 2014 | DOI: 10.1002/cjoc.201400003

      Thumbnail image of graphical abstract

      The Co0.85Se/Ni0.85Se based dye-sensitized solar cell yielded comparable energy conversion efficiency to that of Pt and Co0.85Se for iodide/triiodide electrolyte. Moreover, for cobalt(II/III) electrolyte, the Co0.85Se/Ni0.85Se based dye-sensitized solar cell performed significantly improved efficiency compared to that of Pt and Co0.85Se.

    4. Broadband Antireflective Superhydrophilic Thin Films with Outstanding Mechanical Stability on Glass Substrates (pages 507–512)

      Lin Yao and Junhui He

      Article first published online: 13 MAR 2014 | DOI: 10.1002/cjoc.201400022

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      A facile approach was developed to fabricate visible/near-infrared antireflective (AR), superhydrophilic and anti-fogging thin films on glass substrates.

    5. SalenZn-bridged D-π-A Dyes For Dye-Sensitized Solar Cells (pages 513–520)

      Yongjian Jia, Faliang Gou, Ran Fang, Huanwang Jing and Zhenping Zhu

      Article first published online: 22 APR 2014 | DOI: 10.1002/cjoc.201300924

      Thumbnail image of graphical abstract

      A series of SalenZn based dyes have been designed and synthesized for dye-sensitized solar cells. The efficiency of DSSCs augments evidently along with the increased tail length of the alkyl substituents. It is also found that the dye owning bis-carboxyl groups induces a remarkable enhancement of the electron injection efficiency and generates higher electron density and voltage.

    6. Random Copolymers Based on Thieno[3,4-c]pyrrole-4,6-dione and Isoindigo Building Blocks for Polymer Solar Cells (pages 521–526)

      Ping Deng, Jian Xiong, Shugang Li, Yibing Wu, Junliang Yang and Qing Zhang

      Article first published online: 17 JUN 2014 | DOI: 10.1002/cjoc.201400316

      Thumbnail image of graphical abstract

      The tactics of using more than one kind of acceptors did result in polymers with broad absorption spectra and appropriate energy levels for polymer solar cell applications.

    7. Theoretical Investigation on Structures, Stabilities, and Hydrolysis Reactions of Small RuO2 Nanoclusters (pages 527–537)

      Hao Dong, Zhonghua Zan and Xin Zhou

      Article first published online: 13 MAR 2014 | DOI: 10.1002/cjoc.201300912

      Thumbnail image of graphical abstract

      The calculated results show that H2O can be more easily split on the cationic ruthenium oxide clusters than on the neutral clusters.

    8. Design, Synthesis and Bioactivities Evaluation of Novel Quinazoline Analogs Containing Oxazole Units (pages 538–544)

      Xuehui Hou, Jingyu Zhang, Xuan Zhao, Liming Chang, Ping Hu and Hongmin Liu

      Article first published online: 17 JUN 2014 | DOI: 10.1002/cjoc.201400271

      Thumbnail image of graphical abstract

      Novel quinazoline derivatives were designed and synthesized, which were potential epidermal Growth factors receptor (EGFR) inhibitors. Their biological activities were evaluated for their anti-proliferative activities and EGFR inhibitory potency in vitro.

    9. Mixture Toxicities of Three Pesticides Having Different Time-Toxicity Profiles (pages 545–552)

      Mo Yu, Shushen Liu, Mengchao Wang, Fu Chen and Hanxiao Tang

      Article first published online: 13 JUN 2014 | DOI: 10.1002/cjoc.201400133

      Thumbnail image of graphical abstract

      The mixture toxicities of three pesticides having different time-toxicity profiles are concentration additive, being independent of time, concentration or concentration ratio.

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