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Keywords:

  • cluster compounds;
  • doping;
  • IR spectroscopy;
  • silicon;
  • structure elucidation
Thumbnail image of graphical abstract

Good vibrations: Vibrational spectra of doped silicon clusters are obtained upon IR multiple photon dissociation of their complexes with argon ligands (see figure). The comparison between experiment and calculated spectra of low-lying isomers allows for structural assignments.