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Keywords:

  • nanostructures;
  • metal–organic complexes;
  • Salen complexes;
  • self-assembly;
  • scanning tunneling microscopy
Thumbnail image of graphical abstract

Molecular networks: Chiral and metallized Salen molecules on a Cu(111) are investigated using local probe techniques (see figure). Whereas for the parent Co-Salen molecule no self-assembly is observed, in the metal–organic complexes the growth of large and regular molecular networks is achieved through a target-oriented synthetic design of the local electrostatic dipolar molecular fields.