Communication
A Designed Biosurfactant Protein for Switchable Foam Control
Article first published online: 1 MAR 2011
DOI: 10.1002/cphc.201100082
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue

ChemPhysChem
Special Issue: Jacobus van't Hoff
Volume 12, Issue 8, pages 1426–1429, June 6, 2011
Additional Information
How to Cite
Middelberg, A. P. J. and Dimitrijev-Dwyer, M. (2011), A Designed Biosurfactant Protein for Switchable Foam Control. ChemPhysChem, 12: 1426–1429. doi: 10.1002/cphc.201100082
Publication History
- Issue published online: 24 MAY 2011
- Article first published online: 1 MAR 2011
- Manuscript Received: 1 FEB 2011
Funded by
- Australian Research Council. Grant Number: DP1093056
Keywords:
- surfactants;
- foams;
- proteins;
- stability;
- thin films

Making and breaking foams: A facile method for foam control is reported using a designed biosurfactant. The new biosurfactant is based on a four-helix bundle design which is interfacially active across a broad pH range. At pH 8.5 stable foam forms, yet decreasing the pH to 7.5 causes rapid foam dissipation. This unique behaviour can be linked to subtle molecular and specific-ion effects which lead to switchable changes in the state of the foam thin film (see picture).

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