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Insights into the Induced Ultrafast Electron Delocalization in Fe(CO)5 Using Dark Channel Fluorescence Yield X-Ray Absorption

Authors

  • Dr. Matthias Bauer,

    Corresponding author
    1. Institut für technische Chemie und Polymerchemie, Karlsruhe Institut für Technologie (KIT), Campus Süd, Engesserstraße 18, 76128 Karlsruhe (Germany), Fax:(+49) 721 608-44820
    • Institut für technische Chemie und Polymerchemie, Karlsruhe Institut für Technologie (KIT), Campus Süd, Engesserstraße 18, 76128 Karlsruhe (Germany), Fax:(+49) 721 608-44820
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  • Tom Stalinski,

    1. Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Straße 15, 12489 Berlin (Germany)
    2. FB Physik, Freie Universität Berlin, Arnimalle 14, 14195 Berlin (Germany), Fax:(+49) 30 8062 14757
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  • Prof. Emad F. Aziz

    Corresponding author
    1. Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Straße 15, 12489 Berlin (Germany)
    2. FB Physik, Freie Universität Berlin, Arnimalle 14, 14195 Berlin (Germany), Fax:(+49) 30 8062 14757
    • Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Straße 15, 12489 Berlin (Germany)
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Abstract

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Well-coordinated: L2,3-edge X-ray absorption measurements of Fe(CO)5, carried out for the first time in solution, are discussed (see picture). Using the dark channel fluorescence yield technique, ultrafast delocalization processes on the femtosecond time-scale yield new insights into the electronic structure.

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