Microwave-Assisted Synthesis of Fluorescent Ag Nanoclusters in Aqueous Solution

Authors

  • Dr. Rongqing Li,

    1. Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210000 (China), Fax: (+86) 25-83601769-838
    2. Department of Physics, Huainan Normal University, Huainan 232038 (China)
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  • Dr. Chunlei Wang,

    1. Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210000 (China), Fax: (+86) 25-83601769-838
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  • Dr. Fan Bo,

    1. Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210000 (China), Fax: (+86) 25-83601769-838
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  • Dr. Zhuyuan Wang,

    1. Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210000 (China), Fax: (+86) 25-83601769-838
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  • Dr. Haibao Shao,

    1. Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210000 (China), Fax: (+86) 25-83601769-838
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  • Dr. Shuhong Xu,

    1. Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210000 (China), Fax: (+86) 25-83601769-838
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  • Prof. Dr. Yiping Cui

    Corresponding author
    1. Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210000 (China), Fax: (+86) 25-83601769-838
    • Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210000 (China), Fax: (+86) 25-83601769-838
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Abstract

Fluorescent Ag nanoclusters are of significant interest because they provide the bridge between atomic and nanoparticle behavior in noble metals. Herein, microwave irradiation was originally used for the synthesis of water-soluble fluorescent Ag nanoclusters. As-prepared Ag nanoclusters present red fluorescence emission around 608 nm and a characteristic absorption peak at about 508 nm. Transmission electron microscopy (TEM) shows an average size of 1.6 nm for Ag nanoclusters. The effect of solution pH on the synthesis process and optical properties of Ag nanoclusters was investigated. The pH-dependent present form and adsorption capacity of poly(methacrylic acid, sodium salt) (PMAA) ligands are believed to be the reason for the pH effect.

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