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Benzene Oxidation at Diamond Electrodes: Comparison of Microcrystalline and Nanocrystalline Diamonds

Authors

  • Prof. Yu. V. Pleskov,

    Corresponding author
    1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prosp. 31, 119071 Moscow (Russia)
    • Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prosp. 31, 119071 Moscow (Russia)
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  • Dr. M. D. Krotova,

    1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prosp. 31, 119071 Moscow (Russia)
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  • Dr. V. V. Elkin,

    1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prosp. 31, 119071 Moscow (Russia)
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  • Dr. V. P. Varnin,

    1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prosp. 31, 119071 Moscow (Russia)
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  • I. G. Teremetskaya,

    1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prosp. 31, 119071 Moscow (Russia)
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  • Dr. A. V. Saveliev,

    1. Prokhorov General Physics Institute, Russian Academy of Sciences ul. Vavilova 38, 119991 Moscow (Russia)
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  • Dr. V. G. Ralchenko

    1. Prokhorov General Physics Institute, Russian Academy of Sciences ul. Vavilova 38, 119991 Moscow (Russia)
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Abstract

A comparative study of benzene oxidation at boron-doped diamond (BDD) and nitrogenated nanocrystalline diamond (NCD) anodes in 0.5 M K2SO4 aqueous solution is conducted by using cyclic voltammetry and electrochemical impedance spectroscopy. It is shown by measurements of differential capacitance and anodic current that during the benzene oxidation at the BDD electrode, adsorption of a reaction intermediate occurs, which partially blocks the electrode surface and lowers the anodic current. At the NCD electrode, benzene is oxidized concurrently with oxygen evolution, a (quinoid) intermediate being adsorbed at the electrode. The adsorption and the electrode surface blocking are reflected in the impedance–frequency and impedance–potential complex-plane plots.

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