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Communication
Reversible Binding of Molecular Oxygen to Catecholate and Amidophenolate Complexes of SbV: Electronic and Steric Factors
Article first published online: 23 OCT 2012
DOI: 10.1002/cphc.201200728
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Fukin, G. K., Baranov, E. V., Poddel'sky, A. I., Cherkasov, V. K. and Abakumov, G. A. (2012), Reversible Binding of Molecular Oxygen to Catecholate and Amidophenolate Complexes of SbV: Electronic and Steric Factors. ChemPhysChem, 13: 3773–3776. doi: 10.1002/cphc.201200728
Publication History
- Issue published online: 29 NOV 2012
- Article first published online: 23 OCT 2012
- Manuscript Revised: 2 OCT 2012
- Manuscript Received: 5 SEP 2012
Funded by
- Russian Foundation for Basic Research. Grant Number: 10-03-00921
- President of Russian Federation. Grant Numbers: NSh-1113.2012.3, MK-614.2011.3
Keywords:
- antimony;
- catecholate;
- density functional calculations;
- molecular oxygen;
- steric and electronic factors
Edge of reactivity: The reactions of reversible binding of molecular oxygen to catecholate and amidophenolate complexes of SbV are investigated by analyzing the position of electronic (EHOMO) and steric (G-parameter) factors. The optimal electronic and steric parameters for such type reactions are found.