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Reversible Binding of Molecular Oxygen to Catecholate and Amidophenolate Complexes of SbV: Electronic and Steric Factors

Authors

  • Dr. Georgy K. Fukin,

    Corresponding author
    1. G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, GSP-445, 603950 Nizhny Novgorod (Russia)
    • G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, GSP-445, 603950 Nizhny Novgorod (Russia)
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  • Dr. Evgenii V. Baranov,

    1. G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, GSP-445, 603950 Nizhny Novgorod (Russia)
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  • Dr. Andrey I. Poddel'sky,

    1. G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, GSP-445, 603950 Nizhny Novgorod (Russia)
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  • Prof. Vladimir K. Cherkasov,

    1. G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, GSP-445, 603950 Nizhny Novgorod (Russia)
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  • Prof. Dr. Gleb A. Abakumov

    1. G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, GSP-445, 603950 Nizhny Novgorod (Russia)
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Abstract

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Edge of reactivity: The reactions of reversible binding of molecular oxygen to catecholate and amidophenolate complexes of SbV are investigated by analyzing the position of electronic (EHOMO) and steric (G-parameter) factors. The optimal electronic and steric parameters for such type reactions are found.

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