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Keywords:

  • acetylene;
  • gas storage;
  • metal–organic frameworks;
  • polymers;
  • spectroscopy
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The adsorption of acetylene on CPO-27-M (M[DOUBLE BOND]Fe, Co and Ni) frameworks is studied by FTIR and UV/Vis spectroscopy, as well as calorimetric isotherm measurements, as shown on p. 445 by S. M. Chavan et al. M[BOND]O pairs act as the adsorption sites in these materials and the Ni analogue is the strongest acetylene adsorbent of the series.