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Keywords:

  • intramolecular charge transfer;
  • molecular devices;
  • position effect;
  • redox reaction;
  • supramolecular chemistry
Thumbnail image of graphical abstract

Molecular motion control systems such as bistable rotaxanes or molecular elevators are mostly designed with different binding sites. In this theoretical study, it is demonstrated that, with the use of a redox reaction center and its position effect, it is possible to build a motion control system with identical binding sites.