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Keywords:

  • hydrogen bonds;
  • IR spectroscopy;
  • laser spectroscopy;
  • supersonic expansions;
  • van der Waals forces
Thumbnail image of graphical abstract

Five waters make a pentagon: Formation of particularly stable propofol2(H2O)5 clusters in propofol/water/He expansions is observed. Their origin seems to be related to the formation of particularly stable pentameric water clusters.