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Optimization of Reaction Conditions towards Multiple Types of Framework Isomers and Periodic-Increased Porosity: Luminescence Properties and Selective CO2 Adsorption over N2

Authors

  • Xiao-Liu Wu,

    1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)
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  • Prof. Dr. Feng Luo,

    Corresponding author
    1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)
    • Feng Luo, College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)

      An-Min Zheng, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan (430071), Hubei (China)

      Jian Zhang, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

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  • Dr. Gong-Ming Sun,

    1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)
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  • Prof. Dr. An-Min Zheng,

    Corresponding author
    1. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan (430071), Hubei (China)
    • Feng Luo, College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)

      An-Min Zheng, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan (430071), Hubei (China)

      Jian Zhang, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

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  • Prof. Dr. Jian Zhang,

    Corresponding author
    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)
    • Feng Luo, College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)

      An-Min Zheng, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan (430071), Hubei (China)

      Jian Zhang, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

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  • Prof. Dr. Ming-Biao Luo,

    1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)
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  • Prof. Dr. Wen-Yuan Xu,

    1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)
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  • Yan Zhu,

    1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)
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  • Xiao-Min Zhang,

    1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)
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  • Shu-Yun Huang

    1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou (344000), Jiangxi (China)
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Abstract

Three new metal-organic frameworks (MOFs) were prepared by solvo(hydro)thermolysis and further characterized as framework isomers. The structural transformation from non-porous to porous MOFs and the purity of these products can be modulated by controlling the reaction temperature. The periodic-increased porosity observed was further confirmed by CO2 adsorption isotherms. Owing to the presence of acylamide groups in the pore walls and the flexible nature of the skeleton of these MOFs, highly selective CO2 adsorption over N2 was observed, as well as structure-dependent periodic varieties in luminescence properties.

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