Communication

Honeycomb Porous Framework of Zinc(II): Effective Host for Palladium Nanoparticles for Efficient Three-Component (A3) Coupling and Selective Gas Storage

  1. Kolleboyina Jayaramulu1,
  2. Dr. Kasibhatta K. R. Datta2,
  3. Mothika V. Suresh1,
  4. Gayatri Kumari3,
  5. Dr. Ranjan Datta4,
  6. Prof. Chandrabhas Narayana3,
  7. Prof. Muthusamy Eswaramoorthy2,*,
  8. Prof. Tapas Kumar Maji1,*

Article first published online: 21 JUN 2012

DOI: 10.1002/cplu.201200093

Issue

ChemPlusChem

ChemPlusChem

Volume 77, Issue 9, pages 743–747, September 2012

Additional Information

How to Cite

Jayaramulu, K., Datta, K. K. R., Suresh, M. V., Kumari, G., Datta, R., Narayana, C., Eswaramoorthy, M. and Maji, T. K. (2012), Honeycomb Porous Framework of Zinc(II): Effective Host for Palladium Nanoparticles for Efficient Three-Component (A3) Coupling and Selective Gas Storage. ChemPlusChem, 77: 743–747. doi: 10.1002/cplu.201200093

Author Information

  1. 1

    Molecular Materials Laboratory, Chemistry and Physics of Materials Unit (CPMU), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur, Bangalore 560064 (India), Fax: (+91) 80-2208-2766 www.jncasr.ac.in/tmaji/

  2. 2

    Nanomaterials and Catalysis Lab, CPMU, JNCASR, Bangalore 560064 (India)

  3. 3

    CPMU, JNCASR, Bangalore 560064 (India).

  4. 4

    International Centre for Materials Science, JNCASR, Bangalore 560064 (India)

*Nanomaterials and Catalysis Lab, CPMU, JNCASR, Bangalore 560064 (India)

Publication History

  1. Issue published online: 11 SEP 2012
  2. Article first published online: 21 JUN 2012
  3. Manuscript Revised: 18 MAY 2012
  4. Manuscript Received: 18 APR 2012

Funded by

  • UGC SRF (Govt. of India)
  • CSIR (Govt. of India)

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Keywords:

  • heterogeneous catalysis;
  • selective CO2 uptake;
  • metal–organic frameworks;
  • nanoparticles;
  • zinc
Thumbnail image of graphical abstract

MOF for effective stabilizer for “Pd” and selective host for CO2: A porous, layered MOF system {[Zn(Himdc)(bipy)].DMF} (1; Himdc=4,5-imidazoledicarboxylate, bipy=4,4'-bipyridine) shows selective gas-storage properties, while the polar nanochannels serve as functional scaffold for the stabilization of highly dispersed Pd nanoparticles. The Pd@MOF1 a hybrid is a highly active and recyclable catalyst for the synthesis of propargylamine derivatives through A3 coupling reactions.

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