Ruthenium-Catalyzed Hydrogenation of Bicarbonate in Water

Authors

  • Christopher Federsel,

    1. Leibniz-Institut für Katalyse e. V. (LIKAT) an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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  • Dr. Ralf Jackstell,

    1. Leibniz-Institut für Katalyse e. V. (LIKAT) an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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  • Albert Boddien,

    1. Leibniz-Institut für Katalyse e. V. (LIKAT) an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
    2. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9780
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  • Dr. Gabor Laurenczy,

    1. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9780
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  • Prof. Matthias Beller

    1. Leibniz-Institut für Katalyse e. V. (LIKAT) an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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Abstract

original image

The hydrogenation of bicarbonate in water is achieved by using a ruthenium-based catalytic system. In the presence of dppm as ligand improved yields and catalyst TONs compared to previously known catalyst systems are achieved.

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