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Tailored Ruthenium–N-Heterocyclic Carbene Hybrid Catalytic Materials for the Hydrogenation of Carbon Dioxide in the Presence of Amine

Authors

  • Mathieu Baffert,

    1. Université de Lyon, C2P2, UMR 5265 (CNRS - CPE Lyon - Université Lyon 1), 43 Bd. du 11 Novembre 1918, 69616 Villeurbanne Cedex (France), Fax: (+33) 472431799
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  • Dr. Tarun K. Maishal,

    1. Université de Lyon, C2P2, UMR 5265 (CNRS - CPE Lyon - Université Lyon 1), 43 Bd. du 11 Novembre 1918, 69616 Villeurbanne Cedex (France), Fax: (+33) 472431799
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  • Laurent Mathey,

    1. Université de Lyon, C2P2, UMR 5265 (CNRS - CPE Lyon - Université Lyon 1), 43 Bd. du 11 Novembre 1918, 69616 Villeurbanne Cedex (France), Fax: (+33) 472431799
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  • Prof. Dr. Christophe Copéret ,

    Corresponding author
    1. Université de Lyon, C2P2, UMR 5265 (CNRS - CPE Lyon - Université Lyon 1), 43 Bd. du 11 Novembre 1918, 69616 Villeurbanne Cedex (France), Fax: (+33) 472431799
    2. (Present address) ETH Zürich, Department of Chemistry, Wolfgang-Pauli-Str. 10, 8093 Zurich (Switzerland), Fax: (+41) 446331325
    • Université de Lyon, C2P2, UMR 5265 (CNRS - CPE Lyon - Université Lyon 1), 43 Bd. du 11 Novembre 1918, 69616 Villeurbanne Cedex (France), Fax: (+33) 472431799
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  • Dr. Chloé Thieuleux

    Corresponding author
    1. Université de Lyon, C2P2, UMR 5265 (CNRS - CPE Lyon - Université Lyon 1), 43 Bd. du 11 Novembre 1918, 69616 Villeurbanne Cedex (France), Fax: (+33) 472431799
    • Université de Lyon, C2P2, UMR 5265 (CNRS - CPE Lyon - Université Lyon 1), 43 Bd. du 11 Novembre 1918, 69616 Villeurbanne Cedex (France), Fax: (+33) 472431799
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Abstract

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Hidden depths: Heterogeneous catalysts containing single-site ruthenium–bis-N-heterocyclic carbene (NHC) species are obtained by designing tailored hybrid organic–inorganic materials and in situ transformations, leading to final Ru-NHC units. These catalysts represent promising alternatives to homogeneous complexes with comparable activities (turnover number of ca. 3000).

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