Carbon-Supported Molybdenum Carbide Catalysts for the Conversion of Vegetable Oils

Authors

  • Dr. Junxing Han,

    1. Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028 (P.R. China), Fax: (+86) 571-88273283
    Search for more papers by this author
  • Dr. Jinzhao Duan,

    1. Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028 (P.R. China), Fax: (+86) 571-88273283
    Search for more papers by this author
  • Dr. Ping Chen,

    1. Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028 (P.R. China), Fax: (+86) 571-88273283
    Search for more papers by this author
  • Prof. Hui Lou,

    Corresponding author
    1. Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028 (P.R. China), Fax: (+86) 571-88273283
    • Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028 (P.R. China), Fax: (+86) 571-88273283
    Search for more papers by this author
  • Prof. Xiaoming Zheng,

    1. Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028 (P.R. China), Fax: (+86) 571-88273283
    Search for more papers by this author
  • Dr. Haiping Hong

    1. Department of Material and Metallurgical, South Dakota School of Mines and Technology, Rapid City 57701 (USA)
    Search for more papers by this author

Abstract

Ordered mesoporous carbon (OMC)-supported molybdenum carbide catalysts were successfully prepared in one pot using a solvent-evaporation-induced self-assembly strategy accompanied by a carbothermal hydrogen reduction reaction. Characterization with nitrogen sorption, small-angle XRD, and TEM confirmed that the obtained materials had high surface areas, large pore volumes, ordered mesoporous structures, narrow pore size distributions, and uniform dispersions of molybdenum carbide particles. With nitrogen replaced by hydrogen in the carbothermal reduction reaction, the formation temperature of molybdenum carbide could be reduced by more than 100 °C. By changing the amount of molybdenum precursor added from less than 2 % to more than 5 %, molybdenum carbide structures could be easily regulated from Mo2C to MoC. The catalytic performance of OMC-supported molybdenum carbide catalysts was evaluated by hydrodeoxygenation of vegetable oils. Compared with Mo2C, MoC exhibited high product selectivity and excellent resistance to leaching in the conversion of vegetable oils into diesel-like hydrocarbons.

Ancillary