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Full Paper
Distillate-Range Products from Non-Oil-Based Sources by Catalytic Cascade Reactions
Article first published online: 3 JUL 2012
DOI: 10.1002/cssc.201200092
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Lacarriere, A., Robin, J., Świerczyński, D., Finiels, A., Fajula, F., Luck, F. and Hulea, V. (2012), Distillate-Range Products from Non-Oil-Based Sources by Catalytic Cascade Reactions. ChemSusChem, 5: 1787–1792. doi: 10.1002/cssc.201200092
Publication History
- Issue published online: 5 SEP 2012
- Article first published online: 3 JUL 2012
- Manuscript Received: 3 FEB 2012
- Abstract
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Keywords:
- ethylene;
- heterogeneous catalysis;
- mesoporous materials;
- nickel;
- oligomerization
Abstract
An original two-step process efficiently catalyzed by functionalized mesoporous materials is proposed as a potential route for converting light olefins into long-chain hydrocarbons in the distillate range. In the first step, ethylene can be selectively transformed into C4–C10 olefins with an even number of carbon atoms, over nickel-exchanged AlMCM-41, at 150 °C. When the nickel-catalyzed oligomerization was assisted by a second acid-catalyzed step over H-MCM-41, olefins with chains longer than 10 carbon atoms were mainly produced with a productivity of 180 g g−1 h−1.