Communication

Chemical Activation of a Mononuclear Non-Porphyrinic Manganese Complex using Water as Oxygen Source for the Oxygen Atom Transfer Reaction

  1. Moulay Youness El Kadiri1,
  2. Dr. Sanae El Ghachtouli2,
  3. Dr. Régis Guillot2,
  4. Laurianne Billon2,
  5. Dr. Marie-France Charlot2,
  6. Dr. Eric Framery1,
  7. Prof. Bruno Andrioletti1,*,
  8. Prof. Ally Aukauloo2,3,*

Article first published online: 9 OCT 2012

DOI: 10.1002/cssc.201200440

Issue

ChemSusChem

ChemSusChem

Volume 5, Issue 11, pages 2147–2150, November 2012

Additional Information

How to Cite

El Kadiri, M. Y., El Ghachtouli, S., Guillot, R., Billon, L., Charlot, M.-F., Framery, E., Andrioletti, B. and Aukauloo, A. (2012), Chemical Activation of a Mononuclear Non-Porphyrinic Manganese Complex using Water as Oxygen Source for the Oxygen Atom Transfer Reaction. ChemSusChem, 5: 2147–2150. doi: 10.1002/cssc.201200440

Author Information

  1. 1

    Institut de Chimie et de Biochimie Moléculaires et Supramoléculaires (ICBMS), UMR CNRS 5246, Université Claude Bernard Lyon-1, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne (France), Fax: (+33) 0472-448-160

  2. 2

    Institut de Chimie Moléculaire et des Matériaux d'Orsay, UMR-CNRS 8182, Université de Paris-Sud XI, 91405 Orsay (France), Fax: (+33) 0169-154-756

  3. 3

    CEA, iBiTec-S, Service de Bioénergétique Biologie Structurale et Mécanismes (SB2SM), 91191 Gif-sur-Yvette (France)

*Institut de Chimie et de Biochimie Moléculaires et Supramoléculaires (ICBMS), UMR CNRS 5246, Université Claude Bernard Lyon-1, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne (France), Fax: (+33) 0472-448-160

Publication History

  1. Issue published online: 14 NOV 2012
  2. Article first published online: 9 OCT 2012
  3. Manuscript Revised: 7 AUG 2012
  4. Manuscript Received: 26 JUN 2012

Funded by

  • ANR-TechBioPhyp
  • EU/Energy SOLAR-H2. Grant Number: 212508
  • La Région Rhône Alpes
  • French Ministry of Higher Education

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (329K)

Keywords:

  • bioinorganic chemistry;
  • epoxidation;
  • manganese;
  • oxygen;
  • water activation
Thumbnail image of graphical abstract

Water, a powerful ally: A MnIII complex with an N4O-coordinating ligand and a deprotonated water molecule as sixth ligand is chemically oxidized by a CeIV one-electron oxidant. The results indicate catalytic oxygen atom transfer to alkenes, with the oxygen atom originating from a water molecule. These findings demonstrate the possibility of using water as oxygen source to perform the oxidation of organic substrates.

View Full Article with Supporting Information (HTML) Get PDF (329K)