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Full Paper
Towards Alternatives to Anodic Water Oxidation: Basket-Handle Thiolate FeIII Porphyrins for Electrocatalytic Hydrocarbon Oxidation
Article first published online: 3 SEP 2012
DOI: 10.1002/cssc.201200572
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Li, P., Alenezi, K., Ibrahim, S. K., Wright, J. A., Hughes, D. L. and Pickett, C. J. (2012), Towards Alternatives to Anodic Water Oxidation: Basket-Handle Thiolate FeIII Porphyrins for Electrocatalytic Hydrocarbon Oxidation. ChemSusChem, 5: 2361–2375. doi: 10.1002/cssc.201200572
Publication History
- Issue published online: 3 DEC 2012
- Article first published online: 3 SEP 2012
- Manuscript Received: 7 AUG 2012
Funded by
- EPSRC. Grant Number: EPSRC F047878/1
Keywords:
- electrocatalysis;
- hydrocarbons;
- iron;
- oxidation;
- porphyrins
Abstract
Selective electrocatalytic oxidation of hydrocarbons to alcohols, epoxides or other (higher value) oxygenates should in principal present a useful complementary anodic half-cell reaction to cathodic generation of fuels from water or CO2 viz. an alternative to oxygen evolution. A series of new basket-handle thiolate FeIII porphyrins have been synthesised and shown to mediate anodic oxidation of hydrocarbons, specifically adamantane hydroxylation and cyclooctene epoxidation. We compare yields obtained by electrochemical and chemical oxidation of the thiolate porphyrins and benchmark their behaviour against that of FeIII tetraphenyl porphyrin chloride and its tetrapentafluorophenyl analogue.