Full Paper

You have free access to this content

Photo-active Cobalt Cubane Model of an Oxygen-Evolving Catalyst

Dr. Mark D. Symes¹,
Dr. Daniel A. Lutterman¹,
Dr. Thomas S. Teets¹,
Bryce L. Anderson¹,
Prof. John J. Breen^1,2,
Prof. Daniel G. Nocera^1,*

Article first published online: 3 JAN 2013

DOI: 10.1002/cssc.201200682

Issue

ChemSusChem

Volume 6, Issue 1, pages 65–69, January 2013

Additional Information

How to Cite

Symes, M. D., Lutterman, D. A., Teets, T. S., Anderson, B. L., Breen, J. J. and Nocera, D. G. (2013), Photo-active Cobalt Cubane Model of an Oxygen-Evolving Catalyst. ChemSusChem, 6: 65–69. doi: 10.1002/cssc.201200682

Author Information

¹
Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA, 02139 (USA), Fax: (+1) 617-253-7670
²
Department of Chemistry, Providence College, 1 Cunningham Square, Providence, RI (USA)

Email: Prof. Daniel G. Nocera (nocera@mit.edu)

^*Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA, 02139 (USA), Fax: (+1) 617-253-7670

Publication History

Issue published online: 11 JAN 2013
Article first published online: 3 JAN 2013
Manuscript Received: 12 SEP 2012

Funded by

AFOSR. Grant Number: FA9550-09-1-0689
Chesonis Family Foundation
Jane Coffin Childs Memorial Fund for Medicinal Research
Fannie and John Hertz Foundation

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (634K)

1
N. S. Lewis, D. G. Nocera, Proc. Natl. Acad. Sci. USA 2006, 103, 15729.
2
D. G. Nocera, Inorg. Chem. 2009, 48, 10001.
3
D. Gust, T. A. Moore, A. L. Moore, Acc. Chem. Res. 2009, 42, 1890.
4
D. Abbott, Proc. IEEE 2010, 98, 42.
5
T. R. Cook, D. K. Dogutan, S. Y. Reece, Y. Surendranath, T. S. Teets, D. G. Nocera, Chem. Rev. 2010, 110, 6474.
6
M. W. Kanan, D. G. Nocera, Science 2008, 321, 1072.
7
A nickel-based analogue has also been reported; see
7a
M. Dincă, Y. Surendranath, D. G. Nocera, Proc. Natl. Acad. Sci. USA 2010, 107, 10337.
8
D. K. Bediako, B. Lassalle-Kaiser, Y. Surendranath, J. Yano, V. K. Yachandra, D. G. Nocera, J. Am. Chem. Soc. 2012, 134, 6801.
9
D. K. Zhong, J. Sun, H. Inumaru, D. R. Gamelin, J. Am. Chem. Soc. 2009, 131, 6086.
10
D. K. Zhong, D. R. Gamelin, J. Am. Chem. Soc. 2010, 132, 4202.
11
E. M. P. Steinmiller, K. S. Choi, Proc. Natl. Acad. Sci. USA 2009, 106, 20633.
12
J. A. Seabold, K. S. Choi, Chem. Mater. 2011, 23, 1105.
13
D. K. Zhong, M. Cornuz, K. Sivula, M. Grätzel, D. R. Gamelin, Energy Environ. Sci. 2011, 4, 1759.
14
K. J. McDonald, K. S. Choi, Chem. Mater. 2011, 23, 1686.
15
D. K. Zhong, S. Choi, D. R. Gamelin, J. Am. Chem. Soc. 2011, 133, 18370.
16
Y. Surendranath, M. Dincǎ, D. G. Nocera, J. Am. Chem. Soc. 2009, 131, 2615.
17
D. A. Lutterman, Y. Surendranath, D. G. Nocera, J. Am. Chem. Soc. 2009, 131, 3838.
18
A. J. Esswein, Y. Surendranath, S. Y. Reece, D. G. Nocera, Energy Environ. Sci. 2011, 4, 499.
19
J. J. H. Pijpers, M. T. Winkler, Y. Surendranath, T. Buonassisi, D. G. Nocera, Proc. Natl. Acad. Sci. USA 2011, 108, 10056.
20
E. R. Young, R. Costi, D. G. Nocera, V. Bulović, Energy Environ. Sci. 2011, 4, 2058.
21
S. Y. Reece, J. A. Hamel, K. Sung, T. D. Jarvi, A. J. Esswein, J. J. H. Pijpers, D. G. Nocera, Science 2011, 334, 645.
22
D. G. Nocera, Acc. Chem. Res. 2012, 45, 767.
23
M. Risch, V. Khare, I. Zaharieva, L. Gerencser, P. Chernev, H. Dau, J. Am. Chem. Soc. 2009, 131, 6936.
24
M. W. Kanan, J. Yano, Y. Surendranath, M. Dincǎ, V. K. Yachandra, D. G. Nocera, J. Am. Chem. Soc. 2010, 132, 13692.
25
J. G. McAlpin, Y. Surendranath, M. Dincǎ, T. A. Stich, S. A. Stoian, W. H. Casey, D. G. Nocera, R. D. Britt, J. Am. Chem. Soc. 2010, 132, 6882.
26
J. G. McAlpin, T. A. Stich, C. A. Ohlin, Y. Surendranath, D. G. Nocera, W. H. Casey, R. D. Britt, J. Am. Chem. Soc. 2011, 133, 15444.
27
Y. Surendranath, M. W. Kanan, D. G. Nocera, J. Am. Chem. Soc. 2010, 132, 16501.
28
M. D. Symes, Y. Surendranath, D. A. Lutterman, D. G. Nocera, J. Am. Chem. Soc. 2011, 133, 5174.
29
K. Dimitrou, K. Folting, W. E. Streib, G. Christou, J. Am. Chem. Soc. 1993, 115, 6432.
30
K. Dimitrou, A. D. Brown, K. Folting, G. Christou, Inorg. Chem. 1999, 38, 1834.
31
J. Barber, Inorg. Chem. 2008, 47, 1700.
32
Y. Umena, K. Kawakami, J. R. Shen, N. Kamiya, Nature 2011, 473, 55.
33
K. Dimitrou, A. D. Brown, T. E. Concolino, A. L. Rheingold, G. Christou, Chem. Commun. 2001, 1284.
34
D. M. Cleland, G. Irwin, P. Wagner, D. L. Officer, K. C. Gordon, Chem. Eur. J. 2009, 15, 3682.
Direct Link:
35
D. M. Dattelbaum, K. M. Omberg, J. R. Schoonover, R. L. Martin, T. J. Meyer, Inorg. Chem. 2002, 41, 6071.
36
L. Sacksteder, A. P. Zipp, E. A. Brown, J. Streich, J. N. Demas, B. A. DeGraff, Inorg. Chem. 1990, 29, 4335.
37
J. V. Caspar, T. J. Meyer, J. Phys. Chem. 1983, 87, 952.
38
A. J. Lees, Chem. Rev. 1987, 87, 711.
39
C. Shih, A. K. Museth, M. Abrahamsson, A. M. Blanco-Rodríguez, A. J. Di Bilio, J. Sudhamsu, B. R. Crane, K. L. Ronayne, M. Towrie, A. Vlček, Jr., J. H. Richards, J. R. Winkler, H. B. Gray, Science 2008, 320, 1760.
40
S. Y. Reece, M. R. Seyedsayamdost, J. Stubbe, D. G. Nocera, J. Am. Chem. Soc. 2007, 129, 8500.
41
A. M. Blanco-Rodríguez, M. Towrie, J. Sýkora, S. Záliš, A. Vlček, Jr., Inorg. Chem. 2011, 50, 6122.
42
S. Y. Reece, D. G. Nocera, J. Am. Chem. Soc. 2005, 127, 9448.
43
Z.-H. Loh, S. E. Miller, C. J. Chang, S. D. Carpenter, D. G. Nocera, J. Phys. Chem. A 2002, 106, 11700.
44
Gaussian 03, revision C.02, M. J. Frisch, et al., Gaussian, Inc., Wallingford, CT, 2004, see the Supporting Information for complete reference.
45
A. D. Becke, J. Chem. Phys. 1993, 98, 5648.
46
A. D. Becke, Phys. Rev. A 1988, 38, 3098.
47
C. Lee, W. Yang, R. G. Parr, Phys. Rev. B 1988, 37, 785.
48
P. Flükiger, H. P. Lüthi, S. Portmann, J. Weber, MOLEKEL 4.3: Swiss Center for Scientific Computing, Manno, Switzerland, 2000, www.cscs.ch/molekel.

View Full Article with Supporting Information (HTML) Get PDF (634K)

JOURNAL TOOLS

JOURNAL MENU

FIND ISSUES

FIND ARTICLES

GET ACCESS

FOR CONTRIBUTORS

ABOUT THIS JOURNAL

SPECIAL FEATURES

Photo-active Cobalt Cubane Model of an Oxygen-Evolving Catalyst

ChemSusChem

How to Cite

Author Information

Publication History

Funded by

ARTICLE TOOLS

More content like this

JOURNAL TOOLS

JOURNAL MENU

FIND ISSUES

FIND ARTICLES

GET ACCESS

FOR CONTRIBUTORS

ABOUT THIS JOURNAL

SPECIAL FEATURES

Photo-active Cobalt Cubane Model of an Oxygen-Evolving Catalyst

ChemSusChem

How to Cite

Author Information

Publication History

Funded by

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

More content like this