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Keywords:

  • acetic acid;
  • biomass;
  • furfural;
  • hydrolysis;
  • lignocellulose

Abstract

Furfural and acetic acid are produced with approximately 60 and 90 mol % yield, respectively, upon stripping bagasse with a gaseous stream of HCl/steam and condensing the effluent to water/furfural/acetic acid. The reaction kinetics is 1st order in furfural and 0.5th order in HCl. A process concept with full recycling of the reaction effluents is proposed to reduce the energy demand to <10 tonsteam tonfurfural−1 and facilitate the product recovery through a simple liquid/liquid separation of the condensate into a water-rich and a furfural-rich phase.