Photoreduction of Iron(III) to Iron(0) Nanoparticles for Simultaneous Hydrogen Evolution in Aqueous Solution

Authors

  • Dr. Chuan-Jun Wang,

    1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (P.R. China), Fax: (+86) 10-6255-4670
    Search for more papers by this author
    • These authors contributed equally to this work.

  • Dr. Shuang Cao,

    1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (P.R. China), Fax: (+86) 10-6255-4670
    Search for more papers by this author
    • These authors contributed equally to this work.

  • Dr. Biao Qin,

    1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (P.R. China), Fax: (+86) 10-6255-4670
    Search for more papers by this author
    • These authors contributed equally to this work.

  • Chen Zhang,

    1. College of Chemistry and Engineering, Yunnan Normal University, Kunming 650092 (P.R. China)
    Search for more papers by this author
  • Dr. Ting-Ting Li,

    1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (P.R. China), Fax: (+86) 10-6255-4670
    Search for more papers by this author
  • Prof. Wen-Fu Fu

    Corresponding author
    1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (P.R. China), Fax: (+86) 10-6255-4670
    2. College of Chemistry and Engineering, Yunnan Normal University, Kunming 650092 (P.R. China)
    • Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (P.R. China), Fax: (+86) 10-6255-4670===

    Search for more papers by this author

Abstract

Crystalline Fe nanoparticles were obtained with fluorescein (Fl) as the photosensitizer in triethylamine (TEA) or triethanolamine (TEOA) aqueous solution with FeCl3 as the Fe precursor under bright visible-light light-emitting diode (LED) irradiation. Photoinduced electron transfer from excited state Fl* and Fl to Fe3+ produced the Fe nanoparticles, which served as the active catalyst for in situ photocatalytic hydrogen production with Fl and TEA or TEOA as the photosensitizer and electron donors, respectively, in the same system. Robust hydrogen production activities were observed under the Fe nanoparticle photoreduction conditions in basic solution, and tens of milliliters of hydrogen were obtained over prolonged LED irradiation. If inorganic support materials such as NH2-MCM-41 or reduced graphene oxide were introduced, dispersed nanoparticles with different sizes and shapes were deposited on the supports, which led to variously enhanced hydrogen production activities. The relationships between the morphologies of the Fe/H2N-MCM-41 or Fe/graphene composites generated in situ and the hydrogen production activities were investigated systematically.

Ancillary