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Iron Oxide Encapsulated by Ruthenium Hydroxyapatite as Heterogeneous Catalyst for the Synthesis of 2,5-Diformylfuran

Authors

  • Prof. Zehui Zhang,

    Corresponding author
    1. Key Laboratory of Catalysis and Material Sciences, State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, MinYuan Road 182, Wuhan (PR China), Fax: (+86) 27-67842752
    • Key Laboratory of Catalysis and Material Sciences, State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, MinYuan Road 182, Wuhan (PR China), Fax: (+86) 27-67842752

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  • Ziliang Yuan,

    1. Key Laboratory of Catalysis and Material Sciences, State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, MinYuan Road 182, Wuhan (PR China), Fax: (+86) 27-67842752
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  • Dr. Dingguo Tang,

    1. Key Laboratory of Catalysis and Material Sciences, State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, MinYuan Road 182, Wuhan (PR China), Fax: (+86) 27-67842752
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  • Dr. Yongshen Ren,

    1. Key Laboratory of Catalysis and Material Sciences, State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, MinYuan Road 182, Wuhan (PR China), Fax: (+86) 27-67842752
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  • Dr. Kangle Lv,

    1. Key Laboratory of Catalysis and Material Sciences, State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, MinYuan Road 182, Wuhan (PR China), Fax: (+86) 27-67842752
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  • Dr. Bing Liu

    1. Key Laboratory of Catalysis and Material Sciences, State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, MinYuan Road 182, Wuhan (PR China), Fax: (+86) 27-67842752
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Abstract

Magnetic γ-Fe2O3 nanocrystallites encapsulated by hydroxyapatite (HAP), HAP@γ-Fe2O3, were prepared followed by cation exchange of Ca2+ on the external HAP surface with Ru3+ to give the γ-Fe2O3@HAP-Ru catalyst. The structure of the as-prepared catalyst was characterized, and its catalytic activity was studied in the aerobic oxidation of 5-hydroxymethylfurfural (HMF). γ-Fe2O3@HAP-Ru showed a high catalytic activity for the aerobic oxidation of HMF into 2,5-diformylfuran (DFF). A high DFF yield of 89.1 % with an HMF conversion of 100 % was obtained after 4 h at 90 °C. Importantly, the synthesis of DFF from fructose was realized by two consecutive steps. The dehydration of fructose in the presence of a magnetic acid catalyst (Fe3O4@SiO2[BOND]SO3H) produced HMF in a yield of 90.1 %. Then the Fe3O4@SiO2[BOND]SO3H catalyst was removed from the reaction solution with a permanent magnet, and HMF in the resulting solution was further oxidized to DFF with a yield of 79.1 % based on fructose. The synthesis of DFF from fructose by two steps avoids the tedious separation of the intermediate HMF, which saves time and energy.

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