A Dendritic Oligothiophene Ruthenium Sensitizer for Stable Dye-Sensitized Solar Cells (pages 761–768)
Frédéric Sauvage, Markus K. R. Fischer, Amaresh Mishra, Shaik M. Zakeeruddin, Mohammad K. Nazeeruddin, Peter Bäuerle and Michael Grätzel
Version of Record online: 30 JUN 2009 | DOI: 10.1002/cssc.200900058
A ruthenium(II)-based complex containing a dendritic terthiophene unit attached to a 2,2'-bipyridine ligand is prepared, and tested in a dye-sensitized solar cell. The use of this complex as sensitizer together with a nanocrystalline anatase TiO2 photoanode results in good performance with excellent stability, featuring a maximum photon-to-electron conversion efficiency of ca. 7.4 % in combination with a 3-methoxypropionitrile-based iodine/iodide redox electrolyte.