Structure–Function Correlations for Ru/CNT in the Catalytic Decomposition of Ammonia (pages 226–230)
Weiqing Zheng, Jian Zhang, Bo Zhu, Raoul Blume, Yonglai Zhang, Klaus Schlichte, Robert Schlögl, Ferdi Schüth and Dang Sheng Su
Version of Record online: 12 FEB 2010 | DOI: 10.1002/cssc.200900217
Ruthenium-based catalysts exhibit promising properties in both ammonia decomposition and synthesis. A fundamental study on the structural effects of CNTs, when used as supports for Ru nanoparticles, and on the localization of Ru nanoparticles, on ammonia decomposition is reported. The observed trend is counter-intuitive to the general notion about the beneficial effect of a reduced particle size for better activity in a nonselective reaction.