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Synthesis, Structures, and Luminescent Properties of d10 Group 12 Metal Complexes with Substituted 2,2′-Bipyridine Ligands

  1. Xiao-ming Liu1,
  2. Xiao-yue Mu1,
  3. Hong Xia1,2,
  4. Ling Ye1,
  5. Wei Gao1,
  6. Hao-yu Wang1,
  7. Ying Mu1

Article first published online: 24 AUG 2006

DOI: 10.1002/ejic.200600262

Issue

European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Volume 2006, Issue 21, pages 4317–4323, November 2006

Additional Information

How to Cite

Liu, X.-m., Mu, X.-y., Xia, H., Ye, L., Gao, W., Wang, H.-y. and Mu, Y. (2006), Synthesis, Structures, and Luminescent Properties of d10 Group 12 Metal Complexes with Substituted 2,2′-Bipyridine Ligands. European Journal of Inorganic Chemistry, 2006: 4317–4323. doi: 10.1002/ejic.200600262

Author Information

  1. 1

    Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, School of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, People’s Republic of China, Fax: +86-431-5193421

  2. 2

    State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Technology, Jilin University, Changchun 130012, People’s Republic of China

Publication History

  1. Issue published online: 23 OCT 2006
  2. Article first published online: 24 AUG 2006
  3. Manuscript Received: 25 MAR 2006

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Keywords:

  • Group 12 metal complexes;
  • 2,2′-Bipyridine;
  • Solid-state structures;
  • Luminescence

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Abstract

Four d10 group 12 metal complexes, 6-(2-methoxyphenyl)-2,2′-bipyridinezinc dichloride (2a), -mercury dichloride (2b), 6-[2-(dimethylamino)phenyl]-2,2′-bipyridinezinc dichloride (2c), and -mercury dichloride (2d), were synthesized and the structures determined by single-crystal X-ray crystallography. Complexes 2a and 2b are four-coordinate and adopt a distorted tetrahedral geometry, while complexes 2c and 2d are five-coordinate with a distorted trigonal bipyramidal geometry for the metal center. Luminescent properties of complexes 2a–2d in both solution and the solid state were studied. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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