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Microreview
Alternating and Non-Alternating Pd-Catalysed Co- and Terpolymerisation of Carbon Monoxide and Alkenes
Article first published online: 16 APR 2007
DOI: 10.1002/ejic.200700024
Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
García Suárez, E. J., Godard, C., Ruiz, A. and Claver, C. (2007), Alternating and Non-Alternating Pd-Catalysed Co- and Terpolymerisation of Carbon Monoxide and Alkenes. Eur. J. Inorg. Chem., 2007: 2582–2593. doi: 10.1002/ejic.200700024
Publication History
- Issue published online: 18 JUN 2007
- Article first published online: 16 APR 2007
- Manuscript Received: 8 JAN 2007
Funded by
- Spanish Ministerio de Educación y Ciencia. Grant Numbers: CTQ2004-04412/BQU, CSD2006-0003
- Generalitat de Catalunya. Grant Number: 2005SGR007777
- European Commission (EC). Grant Number: HPRN-CT-2002-00196
- Abstract
- Article
- References
- Cited By
Keywords:
- Polymerisation;
- Polyketones;
- Palladium;
- Carbon monoxide;
- Alkenes
Abstract
The co- and terpolymerisation of carbon monoxide and alkenes are usually catalysed by palladium complexes, and the properties of the produced polyketones can be finely tuned by an appropriate choice of catalyst and olefinic monomer. After a general overview of the topic, selected recent advances in this field are described. The use of palladium systems containing modified diphosphane and/or new phosphorus-based ligands, and the results obtained using a series of modular N and S ligands, including chiral ligands, in CO/styrene co- and terpolymerisations are reported. The use of new P-O ligands in non-alternating CO/ethene copolymerisation is also described. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)