Short Communication

Complexation of 2,6-Bis(3-pyrazolyl)pyridine–Bis(thiocyanato)iron(II) with a Bridging 4,4′-Bipyridine: A New Example of a Dinuclear Spin Crossover Complex

  1. Dalila Fedaoui1,2,
  2. Yacine Bouhadja2,
  3. Abdellah Kaiba2,
  4. Philippe Guionneau2,
  5. Jean-François Létard2,
  6. Patrick Rosa2

Article first published online: 15 JAN 2008

DOI: 10.1002/ejic.200700708

Issue

European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Volume 2008, Issue 7, pages 1022–1026, March 2008

Additional Information

How to Cite

Fedaoui, D., Bouhadja, Y., Kaiba, A., Guionneau, P., Létard, J.-F. and Rosa, P. (2008), Complexation of 2,6-Bis(3-pyrazolyl)pyridine–Bis(thiocyanato)iron(II) with a Bridging 4,4′-Bipyridine: A New Example of a Dinuclear Spin Crossover Complex. Eur. J. Inorg. Chem., 2008: 1022–1026. doi: 10.1002/ejic.200700708

Author Information

  1. 1

    Department of Chemistry, University of Annaba, Sidi-Ammar 23200, Algeria

  2. 2

    ICMCB, CNRS, Université Bordeaux 1 87, avenue du Dr. A. Schweitzer 33608 Pessac cedex, France, Fax: +33-540002649

Publication History

  1. Issue published online: 19 FEB 2008
  2. Article first published online: 15 JAN 2008
  3. Manuscript Received: 6 JUL 2007

Funded by

  • CNRS
  • Région Aquitaine
  • EU NEX MAGMANET

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Keywords:

  • Spin crossover;
  • Magnetic properties;
  • Iron;
  • Dinuclear complexes

Abstract

Investigation of the coordination behavior of 2,6-bis(3-pyrazolyl)pyridine–bis(thiocyanato)iron(II) towards bridging ligands led to the discovery of a novel dinuclear complex showing spin-crossover. Chemical and structural characterization and a first report of physical properties are presented.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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